Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl·BF3 and their addition to aromatic aldehydes and activated ketones.
نویسندگان
چکیده
Treatment of pyridines, quinoline and methylthiopyrazine with the frustrated Lewis pair TMPMgCl·BF(3) (1) leads to organotrifluoro borates which react readily with a variety of aromatic aldehydes in the absence of a transition metal catalyst.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 21 شماره
صفحات -
تاریخ انتشار 2013